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Studies in CuInS2 based solar cells, including ZnS and In2S3 buffer layers

Identifieur interne : 000465 ( Main/Repository ); précédent : 000464; suivant : 000466

Studies in CuInS2 based solar cells, including ZnS and In2S3 buffer layers

Auteurs : RBID : Pascal:13-0363150

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English descriptors

Abstract

The influence of the growth conditions on the surface chemistry and on the homogeneity of the chemical composition of CuInS2 (CIS) thin films, prepared by sequential evaporation of metallic precursors in presence of elemental sulfur in a two-stage process, was studied by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). It was found that the growth temperature affects the phase in which this compound grows. The samples deposited at temperatures around 500 °C (2nd stage) contain mainly the CuInS2 phase; however, secondary phases like In2S3, Cu2S were additionally identified at the surface and in the bulk of CuInS2 samples deposited at temperatures greater than 550 °C. Also, the elemental composition of the layers constituting the Glass/Mo/CulnS2/buffer/ZnO structure was studied through Auger electron spectroscopy (AES) depth profile measurements. AES measurements carried out across the Class/Mo/CulnS2/buffer/ZnO heterojunction gave evidence of Cu diffusion from the CuInS2 layer towards the rest of the layers constituting the device, and of the formation of a MoS2 layer in the Mo/CuInS2 interface. The performance of CuInS2-based solar cells fabricated using CBD (chemical bath deposition) deposited ZnS as buffer layer was compared to that of cells fabricated using CBD deposited In2S3 as buffer.

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Pascal:13-0363150

Le document en format XML

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<title xml:lang="en" level="a">Studies in CuInS
<sub>2</sub>
based solar cells, including ZnS and In
<sub>2</sub>
S
<sub>3</sub>
buffer layers</title>
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<name sortKey="Calderon, C" uniqKey="Calderon C">C. Calderon</name>
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<s1>Departamento de Física, Universidad Nacional de Colombia</s1>
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<name sortKey="Oyola, J S" uniqKey="Oyola J">J. S. Oyola</name>
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<name sortKey="Bartolo Perez, P" uniqKey="Bartolo Perez P">P. Bartolo-Perez</name>
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<name sortKey="Gordillo, G" uniqKey="Gordillo G">G. Gordillo</name>
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<term>Auger electron spectrometry</term>
<term>Buffer layer</term>
<term>Buffer system</term>
<term>Chemical bath deposition</term>
<term>Chemical composition</term>
<term>Copper</term>
<term>Copper sulfide</term>
<term>Depth profile</term>
<term>Diffusion</term>
<term>Evaporation</term>
<term>Glass</term>
<term>Heterojunction</term>
<term>Heterostructures</term>
<term>Homogeneity</term>
<term>Indium sulfide</term>
<term>Interface</term>
<term>Molybdenum</term>
<term>Multistage circuit</term>
<term>Multistage method</term>
<term>Performance evaluation</term>
<term>Solar cell</term>
<term>Sulfur</term>
<term>Surface chemistry</term>
<term>Ternary compound</term>
<term>Thin film</term>
<term>X ray diffraction</term>
<term>X-ray photoelectron spectra</term>
<term>Zinc oxide</term>
<term>Zinc sulfide</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Cellule solaire</term>
<term>Chimie surface</term>
<term>Homogénéité</term>
<term>Composition chimique</term>
<term>Evaporation</term>
<term>Circuit multiétage</term>
<term>Méthode section divisée</term>
<term>Spectre photoélectron RX</term>
<term>Diffraction RX</term>
<term>Système tampon</term>
<term>Spectrométrie Auger</term>
<term>Profil profondeur</term>
<term>Hétérojonction</term>
<term>Diffusion(transport)</term>
<term>Evaluation performance</term>
<term>Dépôt bain chimique</term>
<term>Composé ternaire</term>
<term>Sulfure de cuivre</term>
<term>Sulfure d'indium</term>
<term>Sulfure de zinc</term>
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<term>Couche mince</term>
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<term>Verre</term>
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<term>66</term>
<term>CuInS2</term>
<term>ZnS</term>
<term>In2S3</term>
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<div type="abstract" xml:lang="en">The influence of the growth conditions on the surface chemistry and on the homogeneity of the chemical composition of CuInS
<sub>2</sub>
(CIS) thin films, prepared by sequential evaporation of metallic precursors in presence of elemental sulfur in a two-stage process, was studied by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). It was found that the growth temperature affects the phase in which this compound grows. The samples deposited at temperatures around 500 °C (2nd stage) contain mainly the CuInS
<sub>2</sub>
phase; however, secondary phases like In
<sub>2</sub>
S
<sub>3</sub>
, Cu
<sub>2</sub>
S were additionally identified at the surface and in the bulk of CuInS
<sub>2</sub>
samples deposited at temperatures greater than 550 °C. Also, the elemental composition of the layers constituting the Glass/Mo/CulnS
<sub>2</sub>
/buffer/ZnO structure was studied through Auger electron spectroscopy (AES) depth profile measurements. AES measurements carried out across the Class/Mo/CulnS
<sub>2</sub>
/buffer/ZnO heterojunction gave evidence of Cu diffusion from the CuInS
<sub>2</sub>
layer towards the rest of the layers constituting the device, and of the formation of a MoS
<sub>2</sub>
layer in the Mo/CuInS
<sub>2</sub>
interface. The performance of CuInS
<sub>2</sub>
-based solar cells fabricated using CBD (chemical bath deposition) deposited ZnS as buffer layer was compared to that of cells fabricated using CBD deposited In
<sub>2</sub>
S
<sub>3</sub>
as buffer.</div>
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<s0>The influence of the growth conditions on the surface chemistry and on the homogeneity of the chemical composition of CuInS
<sub>2</sub>
(CIS) thin films, prepared by sequential evaporation of metallic precursors in presence of elemental sulfur in a two-stage process, was studied by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). It was found that the growth temperature affects the phase in which this compound grows. The samples deposited at temperatures around 500 °C (2nd stage) contain mainly the CuInS
<sub>2</sub>
phase; however, secondary phases like In
<sub>2</sub>
S
<sub>3</sub>
, Cu
<sub>2</sub>
S were additionally identified at the surface and in the bulk of CuInS
<sub>2</sub>
samples deposited at temperatures greater than 550 °C. Also, the elemental composition of the layers constituting the Glass/Mo/CulnS
<sub>2</sub>
/buffer/ZnO structure was studied through Auger electron spectroscopy (AES) depth profile measurements. AES measurements carried out across the Class/Mo/CulnS
<sub>2</sub>
/buffer/ZnO heterojunction gave evidence of Cu diffusion from the CuInS
<sub>2</sub>
layer towards the rest of the layers constituting the device, and of the formation of a MoS
<sub>2</sub>
layer in the Mo/CuInS
<sub>2</sub>
interface. The performance of CuInS
<sub>2</sub>
-based solar cells fabricated using CBD (chemical bath deposition) deposited ZnS as buffer layer was compared to that of cells fabricated using CBD deposited In
<sub>2</sub>
S
<sub>3</sub>
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<s0>Cellule solaire</s0>
<s5>01</s5>
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<fC03 i1="01" i2="X" l="ENG">
<s0>Solar cell</s0>
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<s5>02</s5>
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<s5>02</s5>
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<s5>03</s5>
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<s0>Homogeneidad</s0>
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<s5>04</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s0>Evaporation</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Evaporation</s0>
<s5>05</s5>
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<fC03 i1="05" i2="X" l="SPA">
<s0>Evaporación</s0>
<s5>05</s5>
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<s5>06</s5>
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<s0>Méthode section divisée</s0>
<s5>07</s5>
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<fC03 i1="07" i2="X" l="ENG">
<s0>Multistage method</s0>
<s5>07</s5>
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<s0>Spectre photoélectron RX</s0>
<s5>08</s5>
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<fC03 i1="08" i2="3" l="ENG">
<s0>X-ray photoelectron spectra</s0>
<s5>08</s5>
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<s5>09</s5>
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<s5>09</s5>
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<s5>09</s5>
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<s0>Système tampon</s0>
<s5>10</s5>
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<s5>10</s5>
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<s0>Sistema amortiguador</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Spectrométrie Auger</s0>
<s5>11</s5>
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<fC03 i1="11" i2="X" l="ENG">
<s0>Auger electron spectrometry</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Espectrometría Auger</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Profil profondeur</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Depth profile</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Perfil profundidad</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Hétérojonction</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Heterojunction</s0>
<s5>13</s5>
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<s5>13</s5>
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<s5>14</s5>
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<s5>14</s5>
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<s5>15</s5>
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<s0>Performance evaluation</s0>
<s5>15</s5>
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<s0>Evaluación prestación</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Dépôt bain chimique</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Chemical bath deposition</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Depósito baño químico</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Composé ternaire</s0>
<s5>22</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Ternary compound</s0>
<s5>22</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Compuesto ternario</s0>
<s5>22</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Sulfure de cuivre</s0>
<s5>23</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG">
<s0>Copper sulfide</s0>
<s5>23</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA">
<s0>Cobre sulfuro</s0>
<s5>23</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Sulfure d'indium</s0>
<s5>24</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Indium sulfide</s0>
<s5>24</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Indio sulfuro</s0>
<s5>24</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Sulfure de zinc</s0>
<s5>25</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Zinc sulfide</s0>
<s5>25</s5>
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<fC03 i1="20" i2="X" l="SPA">
<s0>Zinc sulfuro</s0>
<s5>25</s5>
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<s0>Couche tampon</s0>
<s5>26</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG">
<s0>Buffer layer</s0>
<s5>26</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA">
<s0>Capa tampón</s0>
<s5>26</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE">
<s0>Couche mince</s0>
<s5>27</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG">
<s0>Thin film</s0>
<s5>27</s5>
</fC03>
<fC03 i1="22" i2="X" l="SPA">
<s0>Capa fina</s0>
<s5>27</s5>
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<fC03 i1="23" i2="X" l="FRE">
<s0>Soufre</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>28</s5>
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<fC03 i1="23" i2="X" l="ENG">
<s0>Sulfur</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>28</s5>
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<fC03 i1="23" i2="X" l="SPA">
<s0>Azufre</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>28</s5>
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<fC03 i1="24" i2="X" l="FRE">
<s0>Verre</s0>
<s5>29</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG">
<s0>Glass</s0>
<s5>29</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA">
<s0>Vidrio</s0>
<s5>29</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>Molybdène</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>30</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG">
<s0>Molybdenum</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>30</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA">
<s0>Molibdeno</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>30</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE">
<s0>Oxyde de zinc</s0>
<s5>31</s5>
</fC03>
<fC03 i1="26" i2="X" l="ENG">
<s0>Zinc oxide</s0>
<s5>31</s5>
</fC03>
<fC03 i1="26" i2="X" l="SPA">
<s0>Zinc óxido</s0>
<s5>31</s5>
</fC03>
<fC03 i1="27" i2="3" l="FRE">
<s0>Hétérostructure</s0>
<s5>32</s5>
</fC03>
<fC03 i1="27" i2="3" l="ENG">
<s0>Heterostructures</s0>
<s5>32</s5>
</fC03>
<fC03 i1="28" i2="X" l="FRE">
<s0>Cuivre</s0>
<s2>NC</s2>
<s5>33</s5>
</fC03>
<fC03 i1="28" i2="X" l="ENG">
<s0>Copper</s0>
<s2>NC</s2>
<s5>33</s5>
</fC03>
<fC03 i1="28" i2="X" l="SPA">
<s0>Cobre</s0>
<s2>NC</s2>
<s5>33</s5>
</fC03>
<fC03 i1="29" i2="X" l="FRE">
<s0>Interface</s0>
<s5>34</s5>
</fC03>
<fC03 i1="29" i2="X" l="ENG">
<s0>Interface</s0>
<s5>34</s5>
</fC03>
<fC03 i1="29" i2="X" l="SPA">
<s0>Interfase</s0>
<s5>34</s5>
</fC03>
<fC03 i1="30" i2="X" l="FRE">
<s0>8460J</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE">
<s0>8105K</s0>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="32" i2="X" l="FRE">
<s0>6630P</s0>
<s4>INC</s4>
<s5>58</s5>
</fC03>
<fC03 i1="33" i2="X" l="FRE">
<s0>66</s0>
<s4>INC</s4>
<s5>59</s5>
</fC03>
<fC03 i1="34" i2="X" l="FRE">
<s0>CuInS2</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fC03 i1="35" i2="X" l="FRE">
<s0>ZnS</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fC03 i1="36" i2="X" l="FRE">
<s0>In2S3</s0>
<s4>INC</s4>
<s5>84</s5>
</fC03>
<fC03 i1="37" i2="X" l="FRE">
<s0>ZnO</s0>
<s4>INC</s4>
<s5>85</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Chalcopyrite</s0>
<s5>17</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Chalcopyrite</s0>
<s5>17</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Calcopirita</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="X" l="FRE">
<s0>Dispositif optoélectronique</s0>
<s5>18</s5>
</fC07>
<fC07 i1="02" i2="X" l="ENG">
<s0>Optoelectronic device</s0>
<s5>18</s5>
</fC07>
<fC07 i1="02" i2="X" l="SPA">
<s0>Dispositivo optoelectrónico</s0>
<s5>18</s5>
</fC07>
<fC07 i1="03" i2="X" l="FRE">
<s0>Composé II-VI</s0>
<s5>19</s5>
</fC07>
<fC07 i1="03" i2="X" l="ENG">
<s0>II-VI compound</s0>
<s5>19</s5>
</fC07>
<fC07 i1="03" i2="X" l="SPA">
<s0>Compuesto II-VI</s0>
<s5>19</s5>
</fC07>
<fN21>
<s1>343</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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